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Gossip Girls actress Leighton Meester, who is best known for her portrayal of Blair Waldorf on The CW network drama, is featured wearing some provocative lingerie in the December 2009 edition of GQ. The GQ Men of the Year issue is covered by Star Trek actor Chris Pine and touts Meester as Obsession of the Year.

The 23-year-old signed a recording contract in April 2009 with Universal Republic. Her first single Somebody to Love hit radio stations on October 13 and was available for digital download the next day.

Meester was on hand at American Eagle Outfitters in Time Square earlier today, performing a five song set – check it out below.

View more photos and GQ photo shoot stills on second video.