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In January 2005, Pitt and Aniston announced they had decided to separate. Two months later Jenn filed for divorce, citing irreconcilable differences. Pitt and Aniston’s divorce was finalized on October 2, 2005. And since then, their relationship still remains tabloid fodder, mainly because just a few weeks after Jennifer filed for divorce, Brad was spotted with Angelina Jolie. And the rest is history!