Their romance started off as a scandal, but Angelina Jolie and Brad Pitt made it official on August 28th, 2014.
On September 19th, 2016, Jolie filed for divorce from Brad Pitt, as first reported by TMZ.
Take a look back at their romance through the years, from the set of Mr. & Mrs Smith to reports of marital strife.
Mr. & Mrs. Smith 2005 Premiere
David Matalon poses with Brad Pitt, Producer Arnon Milchan, Angelina Jolie and News Corp. President/Chief operating officer Peter Chernin at the premiere of 'Mr. & Mrs. Smith' at the Mann Village Theater in Westwood, California on June 7th, 2005.
Berlin - February 2006
Jolie adopted Zahara from an Ethiopian orphanage on July 6th, 2005, and Pitt legally adopted her (and older brother, Maddox) in January 2006. The couple (with Zahara and Maddox) are pictured above in Berlin a month after the adoption was complete.
A Jolie-Pitt Baby Is Born
Jolie gave birth to the couple's first biological child, Shiloh on May 27th, 2006 in Namibia, Africa.
2007 Golden Globes
Brad Pitt and Angelina Jolie pose for photos at the 64th Annual Golden Globe Awards at the Beverly Hilton in Beverly Hills, CA on January 15, 2007 in Beverly Hills, California.
Brad and Pax
Jolie adopted son Pax from Vietnam in March 2007. Pitt adopted him as well a year later.
The couple confirmed that Jolie was pregnant with twins at the 2008 Cannes Film Festival.