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Between raising awareness on world issues, raising six kids and being an A-list movie star, it’s hard to believe that Angelina Jolie has time for anything else, but she does.

Jolie, Bono, Sean Connery, Keith Richards and Catherine Deneuve, are the newest faces on the Louis Vuitton Core Values campaign.

The newest ad features Jolie, without makeup or shoes and wearing her own clothing, sitting on a boat while seemingly enjoying nature in Cambodia’s Siem Reap province. If it weren’t for her own Alto bag draped over her shoulder, you could easily mistake the ad for an Earth Day promotion.

The image, captured by famed and often controversial Annie Leibovitz, was a challenge because the photographer had to work around Jolie’s four older children, who meandered in and out of the area where the pics were being taken.

Vuitton executive vice president Pietro Beccari is thrilled with the outcome of the ad: “I like the fact that it’s a real moment, this travel message we give through personal journeys is a fundamental one for the brand.”

The photos will be released internationally on Wednesday. Jolie was paid handsomely to be part of the ad campaign, and will reportedly donate an undisclosed share of her earnings to charity.

We have been told that the actress wasn’t wearing makeup. Upon closer inspection, that doesn’t appear to be a true statement … unless the image was enhanced after the fact. Check it out below and let us know what you think: