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It probably shouldn’t came as any surprise – his ex-wife says he is a chronic cheater – now a second woman claims she had an affair with Sandra Bullock’s husband, Jesse James.

Tattoo-covered stripper Michelle Smith told Star Magazine that she and James had a two-year relationship during his marriage to the Oscar-winning actress.

In her tell-all interview Smith, who was jailed last year for beating up a cop and arrested for DUI, spills the details of her affair with Jesse — including stories of unprotected sex, kinky requests and intercourse on his office couch.

Melissa, like Michelle McGee, met James online. Jesse, who married Sandra in 2005, contacted Melissa via her MySpace in September 2006 after a photo of her posing in front of a car at a West Coast Choppers party in Long Beach, California sparked his interest.

“I got a message from this guy saying, ‘Nice car…that’s my godfather’s.’ After a few exchanges, he introduced himself as Jesse James and gave me his e-mail address with the name “Vanilla Gorilla” — the nickname Jesse goes by.

Jesse promised Melissa a ride in one of his cars so she traveled to California to take him up on the offer but instead they ended up having sex in his office.

Smith claims they made small talk and took some photos together and then, “I said, ‘Well, I guess I should get going,’ and he said, ‘You don’t have to,’ and moved his chair closer to me and started rubbing my leg. We ended up having sex on his couch,” Melissa details.

The April 5 issue of Star with the Melissa Smith interview is available on newsstands now.