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Many are still trying to come to grips with the latest Hollywood break-up.

Hilary Duff and Mike Comrie are really over?!?

It's sad, but it's true... and it's not an isolated separation. Over the years, a number of seemingly perfect marriages have come to an end, some in scandalous fashion (we still haven't forgiven you, Jesse James) and others in a relatively amicable manner.

They cover the world of acting, music and even politics. Remember how you felt when Kim Kardashian filed for divorce from Kris Humphries? These splits elicited the exact opposite feeling.

Relive the 9 most unexpected Hollywood divorces in recent memory now:

Jennifer Lopez and Marc Anthony
Jennifer Lopez and Marc Anthony have twins together and also had a great life together. But then it all fell apart.

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Alexis DeJoria waited so long to find the right guy.

In Jesse James, she knows she found that guy.

The drag-racing beauty says she had an undeniable connection with him from their very first meeting, and knew he was "The One" right off the bat:

Alexis DeJoria, Jesse James

"We actually met at the races in Dallas. I was racing at the time, and [Jesse] had been friends with my dad [Paul Mitchell billionaire John Paul DeJoria] for a while."

"So he came up to see my dad and the guys that I race with, and that was it. It was the first time we met, and we just hit it off. He has never missed a race since."

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Jesse James married Alexis DeJoria over the weekend.

Hours after his fourth wedding at her father's Malibu estate March 24, the motorcycle mogul shared a sweet pic via his Instagram account. Peep it:

Jesse James and Alexis DeJoria

"Love, wife, family, work ... Life always just finds a way of showing us what is most important," wrote the former West Coast Choppers CEO, 43.

James, who cheated on wife No. 3 Sandra Bullock with a reported four women and went to rehab in 2010, "had tears in his eyes" during the ceremony.

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Is Alexis DeJoria engaged to Jesse James?

According to Hollyscoop, the 43-year-old, who split with Sandra Bullock in 2010 and was engaged to Kat Von D after that, is engaged to drag racer DeJoria, 35.

The fifth time's the charm apparently,

  • Alexis DeJoria Photo
  • Jesse James Smiling

DeJoria is the daughter of Paul Mitchell hair care co-founder John Paul DeJoria. The celebrity gossip site says that drag racing curcuit insiders confirm it's true.

James was married twice before he wed Bullock, and saw his relationships to the Oscar winner and Kat Von D end in some pretty epic cheating scandals.

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Kat Von D and Jesse James are still an item. Despite rumors of a split, they are very much together ... and planning to get married this summer!

A report in this week's Life & Style strongly insinuated that Kat and Jesse went their separate ways. The couple says that's not remotely true.

A fan of Kat's Tweeted to the LA Ink star, "according to tabloids you and Jesse split! Tabloids are so silly." Von D's response: "ha! Silly is correct!"

Jesse James and Kat Von D Photo

Jesse too shot down the rumors on Thursday.

"That is absolutely not true," he told People magazine of the breakup rumors. "We're still going strong. Things are completely good with us."

Moreover, Jesse says they will get married this summer. James got engaged to Von D in January following a scandalous split with Sandra Bullock.

"That day can't come soon enough," Jesse said.

Despite his track record, he says the future is bright. The will-be bride loves him for him ... and Kat's better in bed than Sandra, to boot.

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Proving that their relationship is still going strong, or is going strong again after their rumored breakup, Kat Von D Tweeted proof of her love for Jesse James.

See below. They appear to be locked in a passionate kiss.

Jesse James and Kat Von D started dating in August, after he finalized his divorce with Sandra Bullock, but hit some bumps in the road late last year.

Jesse and Kat Photo

Nice to see that tatted couple is back in full effect.

During their rumored split, Kat was rumored to have reconciled with ex Nikki Sixx, who briefly dated Denise Richards in recent weeks as well. It's a crazy world.

James has kept a low profile since his affair with Michelle McGee (who was recently linked to Charlie Sheen) blew the lid off his double life in March of last year.

It's all good now, though. They recently took a trip together to visit the mother of his daughter Sunny, Jamie Lindemulder. Sunny turned seven on New Year's Day.

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It looked like it was over, with Nikki Sixx and long-distance relationships to blame. But Jesse James and Kat Von D appeared awfully cozy at lunch Saturday.

The couple turned up at the El Compadre Mexican restaurant in West Hollywood, where they chatted and kissed at their table. So much for that ugly split.

It was the first public outing for the motorcycle mogul and the L.A. Ink star since split rumors started flying over her getting back together with Nikki Sixx.

Von D in the Hee Zee

The love life of Jesse James is hard to follow.

Kat has reportedly been unhappy about James' move to Austin, so that his kids can remain close to his ex-wife and their former stepmother, Sandra Bullock.

She's been losing patience with their "weekend fly-back-and-forth relationship" and reports say she ended it, officially or not, by getting back with Sixx.

Maybe Jesse didn't get the memo.

Witnesses at El Compadre said the couple appeared to be in good spirits, polishing off a shared cheese enchilada, leaving a generous tip and peacing out.

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As we hinted earlier this week, Jesse James and Kat Von D were having problems. Now it looks like those problems have led to a full-blown breakup.

Blame Nikki Sixx and plain old geography. Long distance NEVER works.

Here's the latest: Kat Von D, the heavily-tattooed L.A. Ink star, dumped JJ and went back to Motley Crue rocker Sixx, her ex. She and Jesse were fizzling, so that's not shocking. What is surprising is the feud between Kat and ... TLC.

  • Kat Von D and Nikki Sixx Pic
  • Jesse and Kat

For Kat Von D, it's out with the old, in with ... the older.

While filming the current season of L.A. Ink, Kat was dating Jesse James and during that courtship, producers shot footage of her trash talking ex Nikki.

They even went as far as editing an episode, which featured a "Nikki vs. Jesse" theme, posing a potentially awkward sitch for Kat. Her solution? SUE!

According to reports, Kat's "freaked out" and demanding producers cut the footage, lest she take legal action and halt Ink's production immediately.

How bad was her trash talking? We'll never know, since Kat got her way and the material was nixed! Too bad, that would have been really awkward.

In any case, Jesse's out, Nikki's in. You may now return to your lives.

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Jesse James recently relocated to Texas so his kids could be near their former stepmom, Sandra Bullock, even though he cheated on her and she divorced him.

That plan had the added benefit of putting distance between his family and his other ex-wife, Janine Lindemulder, whose parole bars her from leaving California.

It all made sense at the time for the troubled biker, but he could be headed back to the Golden State before long. The reason for that is simple: Kat Von D.

Jesse James and Kat Von D

MANY TATS, ONE LOVE: It's getting serious for Jesse and Kat!

Janine herself muses: “He did everything he could to try and win Sandra back but it didn’t wash and now that he has Kat in his life, why would he stay in Texas?"

“All of his friends are in California and he was like a fish out of water in Austin which is really Sandra’s town. The sad part is that he made the kids move there."

“He’s a narcissist and if it means being with Kat Von D and the publicity that will bring then I’m sure he will go for it," Janine adds. “I guess I should be happy."

Good attitude, Janine. Way to stay positive.

Jesse James Biography

Marcia Valentine Mug Shot Sandra Bullock's husband, Jesse James is CEO of West Coast Choppers, a motorcycle manufacturer, and the host of Motorcycle Mania and... More »
Full Name
Jesse James
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